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For example, suppose you are asked to determine if a solution of sodium carbonate, Na2CO3, is acidic, basic, or neutral Sodium carbonate is the salt of a strong base (NaOH) and a weak acid (HCO3 ) Salts of strong bases and weak acids are basic salts As a basic salt, we know the final answer must be basic (pH above 7)

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V;(P - PIsat)

RT Function Fl reflects vapor-phase nonidealities through @" and 6 , and the effect of pressure on the fugacity of the solid through the exponential Poynting factor For sufficiently P low pressures, both effects are negligible, in which case Fl % 1 and yl % PIsat/ At moderate and high pressures, vapor-phase nonidealities become important, and for very high pressures even the Poynting factor cannot be ignored Since Fl is generally observed to be greater than unity, it is sometimes called an "enhancement factor," because according to Eq (1494) it leads to a solid solubility greater than would obtain in the absence of these pressure-induced effects

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Solubilities at temperatures and pressures above the critical values of the solvent have important applications for supercritical separation processes Examples are extraction of caffeine from coffee beans and separation of asphaltenes from heavy petroleum fractions For a typical solid/vaporequilibrium (SVE) problem, the solidlvapor saturation pressure PIsat very small, is and the saturated vapor is for practical purposes an ideal gas Hence q5yt for pure solute vapor at this pressure is close to unity Moreover, except for very low values of the system pressure P , the solid solubility yl is small, and can be approximated by ,: the vapor-phase fugacity $ coefficient of the solute at infinite dilution Finally, since PISatis very small, the pressure difference P - P F t in the Poynting factor is nearly equal to P at any pressure where this factor is important With these usually reasonable approximations, Eq (1495) reduces to: 1 P v; Fl = - exp RT

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Buffers are solutions that resist a change in pH when an acid or base is added to them The most common type of buffer is a mixture of a weak acid and its conjugate base The weak acid will neutralize any base added, and the weak base of the buffer will neutralize any acid added to the solution The hydronium ion concentration of a buffer can be calculated using an equation derived from the Ka expression: [H3O+ ] = K a [HA] [A ]

and an expression suitable for engineering applications In this equation, PIsat Vf are purespecies properties, found in a handbook or estimated from a suitable correlation Quantity on the other hand, must be computed from a P VT equation of state-one suitable for vapor mixtures at high pressures Cubic equations of state, such as the SoaveRedlich/Kwong (SRK) and PengRobinson (PR) equations, are usually satisfactory for this kind of calculation Equation (1450) for $i, developed in Sec 142, is applicable here, but with a slightly modified combining rule for interaction parameter aij used in calculation of qi Thus, Eq (1444) is replaced by:

aij = (1 - ltj)(aLaj)112

(1497)

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Taking the negative log of both sides yields the Henderson Hasselbalch equation, which can be used to calculate the pH of a buffer: pH = p K a + log [A ] [HA]

The additional binary interaction parameter lij must be found for each i j pair (i # j ) from experimental data By convention, lij = lji and lii = ljj = 0

147 SolidIVapor Equilibrium (SVE) Partial parameter G iis found from Eq (1445):

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